Background: Current treatment options for symptomatic large-to-massive rotator cuff tears
can reduce pain, but failure rates remain high. Surgeons have incorporated synthetic and …

Background: Rotator cuff tears are one of the most common conditions affecting the shoulder.
Because of the difficulty in managing massive rotator cuff tears and the inability of standard …

This paper describes the one-electron interconversions of isolable Ni III and Ni IV complexes
through their reactions with carbon-centered radicals (R•). First, model Ni III complexes are …

This Communication describes studies of Ph–R F (R F = CF 3 or CF 2 CF 3 ) coupling at Pd
complexes of general structure (P t Bu 3 )Pd II (Ph)(R F ). The CF 3 analogue participates in …

A method for the room temperature deoxyfluorination of benzaldehydes and α-ketoesters
using sulfuryl fluoride and Me 4 NF is described. A large scope of aryl and heteroaryl …

A palladium-catalyzed cross-coupling of aryl chlorides/bromides with TMSCF2H is
described. Two different catalysts, Pd (dba) 2/BrettPhos and Pd (P t Bu3) 2, are …

This paper describes the development of Pd-catalyzed inter- and intramolecular direct arylation
using mesylates. Furthermore, a sequential mesylation/arylation protocol using phenols …

An isolable pyridinium trifluoromethoxide salt is prepared from the reaction of 4-dimethylaminopyridine
with the commercially available liquid 2,4-dinitro(trifluoromethoxy)benzene. The …

This article describes a detailed investigation of ligand effects on Ph–CF 3 coupling from
phosphinoferrocene-ligated Pd II (Ph)(CF 3 ) complexes. This study reveals that increasing the …

This paper describes a method for nickel catalyzed intramolecular C–H arylation using aryl
pivalates as electrophiles. The transformation is efficient for the synthesis of diverse …